Dionex Ion Chromatography Systems
Dionex ICS-4000 Capillary HPIC System
This topic describes commands for controlling the ICS-4000.
Also refer to the following topics for standard commands that are available for the ICS-4000 and other similar Dionex devices:
Note:
The selected Filter level determines which commands are displayed in the Commands dialog box. To select the filter level, right-click in the list of commands in the dialog box.
Pump Commands
Command/Property |
Description |
DegasStatus |
Reports the eluent degasser status, either enabled (On) or disabled (Off). When enabled, the degasser vacuum pump turns on and off as needed to maintain a vacuum. |
EluentBottleLevel |
Indicates the volume of liquid (in liters) in the eluent reservoir. To ensure the accuracy of this value, enter the volume of liquid in the reservoir each time you fill the reservoir. |
EluentValve |
Sets the eluent valve position (Open or Closed). |
FastPressurization |
Starts the fast ramping of pressure to the system operating pressure (see PumpPressureRampMode). |
LeakAbort |
Specifies whether to abort the operation when a leak is occurring. |
On, Off, Prime |
Turns the pump on or off, or starts the pump priming function. |
PumpMode |
Indicates whether the pump is on, off, or priming. |
PumpPressureRampMode |
Sets the mode used for fast ramping: NoRamp: The pressure does not ramp-up quickly. The pressure increases at a slower rate, determined by the set flow rate. RampToTargetPressure: The pressure ramps up quickly to the target pressure (see PumpTargetPressure). RampUsingStepPressure: The pressure increases quickly to 3 MPa (500 psi) and then by a series of smaller step increases, each consisting of a small fast ramp up followed by a short period of regular operation. |
PumpPrimeFlowRate |
Sets the pump flow rate during priming. |
PumpRampStatus |
Indicates whether the pump is currently performing the fast ramping function. |
PumpTargetPressure |
Sets the target pressure when PumpPressureRampMode is RampToTargetPressure. Fast ramping stops when the target pressure is reached. |
Pump Pressure Channel Commands
Command/Property |
Description |
Start/stop data acquisition. |
|
Average |
Averages all measured values. ON: Averages all measured values over the step interval (recommended). |
Reports the signal's slope (the difference between the value and the value 1 second ago). Reported in signal unit/second. |
|
Sets the maximum step rate when Step is set to Auto. |
|
Retention |
Reports the signal's retention time. |
Signal |
Reports the current signal value during data acquisition. |
Sets the step for data acquisition. |
Conductivity Detector (CDet) Commands
Commands/Properties |
Description |
Resets all signals delivered by the detector to zero. |
|
CellControl |
Sets the cell control source. Normal—the cell sends a signal to the detector normally. Cell_Electrically_Disconnected—the cell is disconnected from the detector electronics; no signal is sent to the detector. x_mS_Dummy—a signal that simulates a 1, 21, 180, or 3000 mS conductivity response is sent to the detector. |
Conductivity |
Reports the measured conductivity minus the conductivity of the background. The background offset is determined by the last Autozero command. |
Sets the rate at which Chromeleon collects digital data points from the detector. |
|
DataPolarity |
Sets the signal polarity to Normal or Inverted. |
Sets how quickly the detector responds to a change in signal. |
|
Sets the temperature compensation factor, which is used to stabilize conductivity readings. |
|
TotalConductivity |
Reports the measured conductivity with no offset applied (the total conductivity including the background conductivity). |
Electrochemical Detector (EDet) Commands
Commands/Properties |
Description |
Resets all signals delivered by the detector to zero. |
|
CellControl |
Sets the cell control state. On—the cell is on and sends a signal to the detector normally. Off—the cell is off. If a PdH electrode is selected, turning the cell on turns on the PdH electrode power. |
CellStatus |
Reports whether the cell is connected to or disconnected from Chromeleon. |
Sets the rate at which Chromeleon collects digital data points from the detector. |
|
DC_Voltage |
Sets the fixed potential applied to the working electrode, in the range of -2.048V to +2.047V. Setting the voltage automatically turns on the cell. |
Electrode |
Selects the reference electrode type (AgCl, pH, or PdH). |
ElectrodeStatus |
Reports whether the electrode is connected or disconnected. |
IntegratedDataReading |
Reports the data reading at integration. |
Mode |
Sets the operating mode: IntAmp (integrated amperometry) or DCAmp (DC amperometry) |
PdHElectrodePower |
Turns the PdH electrode power on or off. Turning the PdH electrode power on, automatically turns on the cell, and turning the PdH power off, turns off the cell. |
pH.LowerLimit |
Sets the lower limit for pH. An error is reported in the Audit Trail if the pH is lower than this value at the start of acquisition. |
pH.UpperLimit |
Sets the upper limit for pH. An error is reported in the Audit Trail if the pH is higher than this value at the start of acquisition. |
pH.Value |
Reports the current pH value. |
Sets how quickly the detector responds to a change in signal. |
|
SignalValue |
Reports the measured signal minus the background signal. The background offset is determined by the last Autozero command. |
TotalSignalValue |
Reports the measured signal with no offset applied (the total signal including the background). |
Define a waveform (a plot of potential vs. time). |
Charge Detector (QDet) Commands
Commands/Properties |
Description |
Resets all signals delivered by the detector to zero. |
|
CellControl |
Sets the cell control source. Cell_On—the cell is on and sends a signal to the detector normally. Cell_Off—the cell is off. A signal value of 0 is sent to the detector. x_x_mA_Dummy—a signal that simulates a specific current (mA) is sent to the detector. |
Current |
Reports the measured current minus the current of the background. The background offset is determined by the last Autozero command. |
Sets the rate at which Chromeleon collects digital data points from the detector. |
|
DataPolarity |
Sets the signal polarity to Normal or Inverted. |
Sets how quickly the detector responds to a change in signal. |
|
Sets the temperature compensation factor, which is used to stabilize readings. |
|
TotalCurrent |
Reports the measured current with no offset applied (the total current including the background current). |
Voltage |
Sets the potential applied to the cell and turns on the cell. |
Detector Signal Commands
The following commands and properties are available for all detector signal channels (CD, CD_Total, ED, ED_Total, QD, QD_Total).
Command/Property |
Description |
Start/stop data acquisition. |
|
Automatic autozero. |
|
Reports the signal's slope (the difference between the value and the value 1 second ago). Reported in signal unit/second. |
|
Retention |
Reports the signal's retention time. |
Signal |
Reports the current signal value during data acquisition. |
Detector Analog Output Commands
Analog output commands and properties available for all detectors (CD, ED, QD)
Command/Property |
Description |
Sends a positive pulse to the detector’s analog output as an event marker. |
|
Sets the offset (0 to 100%) applied to the recorder output. |
|
Sets the recorder output polarity. |
|
Calibrates the recorder output (Normal, Zero, or Full-Scale). |
|
Sets the full-scale output range of the recorder. |
Temperature Commands (Column_TC, Compartment_TC, Cell_Heater, and Damper_TC)
Command |
Description |
ControlValue |
Reports a number that represents the percentage of the full value of the temperature device. |
Mode |
Sets the mode (On or Off) of the temperature device. |
ReadyTempDelta |
If the difference between the actual temperature and the temperature set point exceeds the ReadyTempDelta value, the state of the temperature device will be NotReady (see TemperatureState). For example, if the temperature is set to 30°C and ReadyTempDelta is set to 1°C, the device enters the Ready state when the actual temperature is between 29° and 31°C. If the actual temperature is outside this range, the device is in the NotReady state. If the ReadyTempDelta is set to None, Chromeleon does not check whether the set point temperature deviates from the actual temperature. In this case, the TemperatureState is always Ready. |
Status |
Reports the temperature status in relation to the set point (Under_temperature, At_setpoint, Over_temperature). |
TemperatureActual |
Reports the current actual temperature of the device. |
TemperatureSet |
Sets the temperature set point for the device. |
TemperatureState |
Reports whether the temperature device is Ready or NotReady. |
Suppressor Commands
Command |
Description |
Current |
Reports the actual suppressor current. |
CurrentSet |
Sets the current supplied to the suppressor (in mA). |
eluent concentrations |
The following properties specify the concentration of eluent. Chromeleon uses the entered concentration to calculate a recommended suppressor current. Carbonate, Bicarbonate, Hydroxide, Tetraborate, H2SO4, MSA, OtherEluent. |
Mode |
Turns the suppressor on or off. |
RecommendedCurrent |
Specifies a recommended suppressor current, based on the entered eluent concentration. |
Type |
Indicates the type of Suppressor installed. |
Voltage |
Reports the suppressor voltage. |
CR-TC Commands
Command |
Description |
CR_TC |
Turns the CR-TC on or off. |
InstCurrent |
Reports the CR-TC current (in mA) when the CR-TC is on. |
InstVoltage |
Reports the CR-TC voltage (in V) when the CR-TC is on. |
Mode |
Reports the CR-TC mode (RFIC_Capillary, Sample_Preparation, Water_Purification_Capillary). The mode is automatically set, based on the installed EGC type and the pump flowrate. |
OperatingMode |
Indicates the operating mode (RFIC, Sample_Preparation, Water_Purification). For RFIC, the pump and EG must be on. For water purification, the pump must be on. |
State Commands
Command |
Description |
HP_Valve_1, HP_Valve_2 |
The following commands are available: State indicates or sets the state of the optional high-pressure valve. A sets the valve to the A position. B sets the valve to the B position. Duration toggles the valve's state after the specified time. |
InjectValve |
The following commands are available: State indicates or sets the state of the injection valve. LoadPosition sets the valve to the load position. InjectPosition sets the valve to the inject position. Duration toggles the valve's state after the specified time. |
LP_Valve_1, LP_Valve_2 |
The following commands are available: State indicates or sets the state of the optional low-pressure valve. Closed closes the valve. Open opens the valve. Duration toggles the valve's state after the specified time. |
Relay_1, Relay_2 |
The following commands are available: State indicates or sets the state of the relay. Closed closes the relay. Open opens the relay. Duration toggles the relay's state after the specified time. The relay-contact closures are normally open. When the relay is closed, current flows to the connected device (turns on the action). |
TTL_1, TTL_2 |
The following commands are available: State indicates or sets the state of the TTL. 0v sets the TTL to 0 volts. 5v sets the TTL to 5 volts. Duration toggles the TTL’s state after the specified time. The TTL outputs are normally at 5 volts. Setting a TTL output to 0 volts turns on the action in the connected device. |
TTL_Input_1, _2, _3, _4 |
State reports the state of the TTL input (0v or 5v) Mode reports the selected TTL Input Mode.
|
Seal Wash Pump and PWM Drive Commands
Command |
Description |
Speed |
Sets the speed in (%) for the seal wash pump or device connected to the PWM Drive. 100% is full speed and 0% is off. |
Mode |
Sets the mode: Off turns off the pump or device. On turns on the pump or device. It remains on until turned off. Interval turns the pump or device on and off at fixed intervals (for example, 1 minute on, 30 minutes off). The on/off intervals continue until the pump or device is turned off. |
OnDuration |
When the Interval mode is selected, OnDuration specifies the length (in minutes) the pump or device is on during each on interval. |
OffDuration |
When the Interval mode is selected, OffDuration specifies the length (in minutes) the pump or device is off during each off interval. |
In addition to the commands listed above, calibration commands for the ICS-4000 are also available (see Ensuring System Wellness for details).